For anyone considering experimentation with TEOS or other similar precursors: only do so in a proper laboratory setting, and with proper level of understanding of chemical safety risks and mitigation strategies. If you think breathing in silica dust is bad (it is), consider breathing in vapors of a precursor chemical that reacts with moisture to produce silica right there, in your lungs or eyes. Add to this the risk of fire or explosion.
Once health and safety have been addressed, this becomes a really interesting topic, as @VegasJames explained. The commercially available materials mentioned in this thread originally are made by Kyocera in Japan. Some are resin-impregnated silica materials, some are silica-impregnated silica (sic!) that can survive being fired in a kiln and still maintaining some ordering of silica nanoparticles that produces the play of color - hence the glass artists using it.
It boils down to semantics whether we call it 'opal‘ or something else - technically speaking it is an artificial material with opal-like structure and it displays opalescence. It would belong to a broad category of photonic crystals. Another example in this category are butterfly wings - again, the colors are due to periodic structures at the micrometer and nanometer scale, not due to pigmentation.
As far as I am concerned, the science of it, and the amazing skills and effort needed to produce such materials make synthetic opals a legitimate lapidary (or, more broadly, artistic) material. Goldstone is trivial by those same measures.