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Let's Rock => Identifications of Materials => Topic started by: Kaljaia on May 03, 2019, 10:14:57 PM

Title: Reasonably certain it's pyrite
Post by: Kaljaia on May 03, 2019, 10:14:57 PM
First time hitting a metallic inclusion. It turned the oil black and smelled like a swamp, so I'm gonna guess pyrite!
In common opal I think, haven't done a hardness test but it cut too soft and smoothly to be a hard agate.

(https://66.media.tumblr.com/6c6e8de941408fe892f21c545951fc9c/tumblr_pqyce4QNkW1rin3o0_1280.jpg)
Title: Re: Reasonably certain it's pyrite
Post by: lithicbeads on May 04, 2019, 07:58:41 AM
Don't forget about marcasite.
Title: Re: Reasonably certain it's pyrite
Post by: Slabbercabber on May 04, 2019, 10:24:30 AM
Psilomelane would be my guess.  Black oil being the clue.
Title: Re: Reasonably certain it's pyrite
Post by: Kaljaia on May 04, 2019, 06:31:53 PM
Psilomelane would be my guess.  Black oil being the clue.

Would manganese have the sulfur smell and rust oxidation tho?
Title: Re: Reasonably certain it's pyrite
Post by: Slabbercabber on May 05, 2019, 06:12:46 AM
I can't answer the smell question as my nose has never been worth much.  Marcasite and pyrite will oxidize but that is not the same as rust.  If you have actual rust then there must be raw iron.  That seems a bit unlikely.
Title: Re: Reasonably certain it's pyrite
Post by: rocks2dust on May 05, 2019, 07:45:13 AM
Would manganese have the sulfur smell and rust oxidation tho?
No. Psilomelane isn't a sulfide. Pyrite (streak is dark brown) and marcasite (streak is black) both give off the sulfurous smell.
Title: Re: Reasonably certain it's pyrite
Post by: irockhound on May 05, 2019, 10:41:34 AM
I have cut a lot of Nipomo Marcasite agate and it always has that odor and will also turn the water black.
Title: Re: Reasonably certain it's pyrite
Post by: Kaljaia on May 05, 2019, 07:58:31 PM
I have cut a lot of Nipomo Marcasite agate and it always has that odor and will also turn the water black.

Yeah, I figure it's at least FeS2, either Marcasite or Pyrite. The individual crystals look more squared off than the organic forms in Marcasite images, but it's hard to tell. The "Rust" I was referring to is the orange powder and pitting on stone in places. It looks like any metallic surface exposed to air has deteriorated. There was no surface indication of metallic inclusions, only some pitting and orange residue. I'm putting together a little local material "sampler" for ID fun. Do you think "iron pyrite" would be an appropriate label?

Cut another stone tonight with metallic flecks, picked up a few miles away! Apparently it is now the season for metallic inclusions.
Title: Re: Reasonably certain it's pyrite
Post by: lithicbeads on May 05, 2019, 09:17:56 PM
The orange powder sounds like decomposed pyrite not marcasite.
Title: Re: Reasonably certain it's pyrite
Post by: irockhound on May 05, 2019, 10:57:12 PM
I would go with the Iron Pyrite label.  Lithic is right with the powder and Marcasite (at least the ones I have collected) when they go bad they tend to go gray to whitish powder.
Title: Re: Reasonably certain it's pyrite
Post by: Kaljaia on May 05, 2019, 11:19:27 PM
Ok, I'll go with that! Thanks for help on the ID!
Title: Re: Reasonably certain it's pyrite
Post by: lithicbeads on May 06, 2019, 06:12:49 AM
Limonite is the breakdown product of pyrite  and not much fun when you think you have found pyrite cubes but get a closer look and see they are falling apart limonite.